glutamic acid as an environmentally friendly catalyst for one-pot synthesis of 4h-chromene derivatives and biological activity

نویسندگان

farhad hatamjafari department of chemistry, faculty of science, tonekabon branch, islamic azad university, tonekabon, iran

چکیده

in this study, the synthesis of 4 h -chromenes of biological activity via a multicomponent reaction of dimedone, aromatic aldehydes and malononitrile catalyzed by glutamic acid as a catalyst was investigated. the structural features of the synthesized compounds were characterized by melting point, ir and 1 h nmr analysis. the catalyst being reported here is cheap, safe to handle and the whole procedure is eco-friendly, milder conditions, one-pot, excellent yields, operational simplicity and ecofriendly preparation are some advantages of this protocol. the compounds were screened for antimicrobial activity. the results showed that these compounds reacted against all the tested bacteria and fungi.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Fe2O3 as an Environmentally Benign Natural Catalyst for One-Pot and Solvent-Free Synthesis of Spiro-4H-Pyran Derivatives

In this work, a simple and economical procedure for the synthesis of spiro-4H-pyranderivatives has been found through the three-component, one-pot condensation of isatin/acenaphthequinone, malononitrile and different reagents including 1, 3-dicrbonyl compounds, naphthol and 4-hydroxycumarin under thermal and solvent-free conditions in the presence ofFe2O<su...

متن کامل

Silica tungstic acid as an efficient and reusable catalyst for the one-pot synthesis of 2-amino-4H-chromene derivatives.

Silica tungstic acid (STA) has been found to be an efficient and reusable solid acid catalyst for the synthesis of 2-amino-4H-chromenes via the three-component reaction of aromatic aldehydes, malononitrile, and β-naphthol. STA as a novel solid acid was characterized by X-ray fluorescence, X-ray diffraction, and Fourier transform infrared spectroscopy.

متن کامل

An Efficient Synthesis of 4H-chromene Derivatives by a One-pot, Three-component Reaction

A facile and efficient one-pot, multicomponent synthesis of 4H-chromenes is reported, through the reaction of arylglyoxalmonohydrates with 1,3-diketones and malononitrile in eTEMPthanol in the presence of L-proline as a catalyst.

متن کامل

Ce-ZSM-11 Zeolite: An Efficient Heterogeneous Catalyst for One-Pot Synthesis of 4H-Pyran Derivatives

ZSM-11 zeolite was synthesized by hydrothermal treatment and cerium ion was incorporated by the ion exchange method.  The catalytic activity of cerium modified ZSM-11 zeolite was tested for the one-pot synthesis of 4H-pyran derivatives by cyclocondensation of aromatic aldehyde, malononitrile, and ethyl acetoacetate. The synthesized catalyst was characterized by Po...

متن کامل

Mefenamic acid as Environmentally Catalyst for Threecomponent Synthesis of Dihydropyrano [2,3-c]Chromene and Pyrano[2,3-d]Pyrimidine Derivatives

Pills of Mefenamic acid were  employed as effective catalysts in the three component reaction of aromatic  aldehydes,  malononitrile,  as  well  as  4-hydroxycoumarin  or  barbituric  acid  in  aqueous solution,  using  reflux  conditions  in  order  to  synthesize  derivatives  of  dihydropyrano[2,3-c]chromene and pyrano[2,3-d]pyrimidine, correspondingly. Among the benefits of this technique, ...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
journal of chemical health risks

جلد ۶، شماره ۲، صفحات ۰-۰

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023